Watch Batteries

The vast majority of watches on the market and in everyday use are battery-powered quartz watches. The batteries are called either watch batteries or button cells, while the larger lithium powered batteries are sometimes called coin cells.

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A basic electronic watch movement. It is powered by a button cell, regulated by a quartz crystal and controlled by a circuit

 

Despite many advantages of the quartz watch when compared to a solely mechanical timepiece, such as being; cheaper to produce, more robust and self-regulating amongst others, there is one downfall of the quartz watch. This is the reliance on chemical batteries to power them.

There are 3 main types of batteries in use in a watch:

  • Mercury
  • Silver Oxide
  • Lithium

Their common names are given in reference to one of the electrodes they use. In the case of the Silver Oxide and Mercury batteries, it is the positive electrode, whereas a Lithium battery is named after its negative electrode.

Mercury batteries have not been manufactured since the 1990s due to health and environmental concerns with the use of mercury.

watch-battery-anatomy2

A watch battery works by converting chemical energy directly into electrical energy.

The watch battery is split into two distinct parts, the anode can (negative) and the cathode can (positive). The anode is a gel containing a mixture of  the negative electrode and the electrolyte. The cathode contains the positive electrode. Each part is surrounded by a metal shell, coloured grey in the above image, which forms the outside of the cell as well as acting as the corresponding positive and negative contact points.

A separator, which is usually a mesh, prevents the electrodes from mixing but allows ions to flow between each half of the cell.

Although the electrodes do not touch one another, they are electrically connected by the electrolyte.

The insulator ensures that the two parts of the casing are held in place and do not touch one another. It also acts as a seal preventing the chemical mixtures from escaping. It is usually made from nylon. Sometimes it is referred to as the gasket.

In simple terms; in a Silver Oxide battery the electrolyte causes the Silver to lose its oxidisation. The electrolyte then passes the oxidisation onto the Zinc. So you start with Silver Oxide and Zinc, and you end with Silver and Zinc Oxide. In the process an electron is released which is the electric charge that we can use. In the below formula Ag is Silver, and Zn is Zinc.

Ag2O + Zn = 2Ag + ZnO

Most watch batteries are Primary Cells, which means they are non-rechargeable. Once the reactions have taken place inside the battery, they cannot be easily undone and so the batteries are discarded. Some watch companies use Lithium-ion batteries that are charged by Solar energy or movement of the watch, such the Seiko Solar or Citizen Eco-Drive. Rechargeable batteries are called Secondary Cells and are generally inferior in performance as a watch battery than Primary Cells.

Watch batteries are Dry Cells, which means that the chemicals used are not free-flowing liquids. They are usually used in the form of a paste, with only enough moisture to allow a current to flow.

In the chart below are the main characteristics of each battery type:

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The Code is the universal name referred to in the battery naming syntax. This is explained more below.

The Electrolyte used in Mercury and Silver Oxide watch batteries is the highly alkaline Sodium Hydroxide.

In Lithium batteries there is slightly more complex chemistry, and so the Electrolyte used is a mixture of Lithium Perchlorate, Propylene Carbonate and Dimethoxyethane.

Nominal Voltage is the average output of the battery over its useful working life.

End Voltage is the lowest amount of voltage the cell will produce before failing.

The Shelf Life is caused by the side reactions that naturally occur even when no load is applied to the battery. These reactions do not produce current and account for a 5 to 20 percent loss of the cell’s original charge per year.

You will see from the graph below that watch batteries all share the common characteristic of having a stable voltage throughout their life, which then drops very rapidly once the End Voltage is reached and the Shelf Life expires.

 

batteries-23

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Battery Cell Capacity

A battery’s capacity is measured in milliamp-hours (mAh). So a battery with a capacity of 10mAh, will last 1 hour if you draw 10 milliamps from it. A basic quartz watch will usually draw around 1/1,000,000th of an amp per hour or 1 microamp (µA).

So we can calculate that a watch with a consumption of 1µA per hour, and a battery with a capacity of 20mAh will work for:

(20mAh x 1000) / 1µA = 20,000 hours

This is roughly 26.4 months. We must multiply the mAh by 1000 because a milliamp is 1000 times greater than a microamp.

Generally speaking the larger the battery, the higher its capacity. Using the Silver Oxide batteries that Renata manufacture as examples, where the diameter of the cell in all cases is 7.9mm;

  • if the cell height is 1.2mm the capacity is 9.5mAh
  • if the cell height is 2.6mm the capacity is 32mAh
  • if the cell height is 5.4mm the capacity is 80mAh

 

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Watch Battery Naming Syntax

Watch batteries have a universal naming syntax. They are used by all major watch brands, however some companies, most notably Renata, also use their own naming system. This is mentioned in more detail below.

The naming syntax is a string of letters and numbers which tell us the type and size of the battery cell.

We have already learnt that the code for Silver Oxide batteries is S, and the code for Lithium batteries is C.

After the code for the type of battery we usually have an R, this just means that the battery cell is Round in shape.

We then have two numbers which tell us the Diameter and the Height of the cell. The Height is always given as the exact amount, although the value does not include a decimal point. For example a height value given as 3 is 3mm, and a height value of 33 is 3.3mm.

The Diameter value given is not always the exact Diameter in millimeters, but is a universal number code. From the chart below we can see that the Code 5 means a diameter of 5.8mm. There is some slight tolerance in the allowed size, however no battery is manufactured outside this. For example you cannot buy a battery that has a diameter of 6.2mm, but you could find one that is 5.9mm.

battery-size-chart

The following letters may appear after the size code to indicate the electrolyte used:

  • P: potassium hydroxide electrolyte
  • S: sodium hydroxide electrolyte
  • no letter: organic electrolyte

At the end of the code you may also find a W, which is an indicator that the battery complies with all the requirements of the international IEC 60086-3 standard for watch batteries.

 

watch-name-syntax1

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Silver Oxide Watch Batteries

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A typical modern Silver Oxide button cell. This example has no Mercury content and it’s code tell us that: Silver Oxide, Round, 9.5mm diameter, 2.7mm high, sodium hydroxide electrolyte, meets international standards

Silver Oxide batteries are available in two main types:

  • Low Drain
  • High Drain

A Low Drain battery has a high internal resistance, which means that the available current is limited. They use sodium hydroxide as the electrolyte. This makes the Low Drain batteries very stable, but means that they cannot be used if a high current or pulse is required, such as if a light is used on the watch or an alarm sounds.

High Drain batteries have a lower internal resistance, and so can be used in watches with secondary functions that require a pulse of high current. They use potassium hydroxide as the electrolyte.

High Drain batteries have a higher rate of self discharge however, and are very likely to leak once their capacity has been discharged.

All Silver Oxide batteries have a chance of leaking and damaging the watch movement. This usually occurs when the battery cell has discharged and some of the highly alkaline electrolyte comes into contact with the Zinc electrode. In such cases electrolysis occurs and Hydrogen gas is produced. The gas can build up and escape from the cell through the insulator, damaging it in the process. Once the seal has been broken the corrosive chemicals inside the battery cell can then escape and cause damage.

Mercury has been used in the past as an inhibitor, to reduce the risk of leakage. The Mercury content was usually around 0.2% of the total composition of the battery, but this practice has largely been discontinued due to environmental concerns with the use of Mercury, and advancements in the construction of the battery cell which make leaks less likely.

You can learn more about watch battery leaks and how to fix them in this article.

Because they use Silver, Silver Oxide batteries are generally considered to be expensive.

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Lithium Watch Batteries

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A typical 3V lithium battery, or coin cell

Lithium batteries are generally used in watches that require frequent high pulses of current for secondary functions. Due to their size the capacity is generally much higher than a Silver Oxide battery, the above cell for example has a capacity of 150mAh.

As they can deliver a constant high current, if the watch movement becomes short circuited, the Lithium battery will drain very quickly.

Due to chemical composition used, there is virtually no risk of Lithium batteries leaking. However Lithium itself is highly combustible, and so if the watch is exposed to extreme heat there is a chance of the battery cell exploding.

When compared to Silver Oxide batteries, as cheaper elements are used, the Lithium coin cells are generally considered to be inexpensive.

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Here we have an example of a Lithium battery that starts with the letter B. This stands for Carbon Monofluoride, which is used as the Cathode. In general it is more expensive and has a lower self-discharge rate than the more usual Manganese Dioxide that is used. However it is not as effective in delivering high pulse currents. As most watches powered by Lithium batteries have special functions that require high pulse currents, Carbon Monofluoride batteries are generally inferior, and are often only ever used as a watch battery because to the layman they have they same shape as the more usual Lithium batteries with a Manganese Dioxide cathode

 

Renata produce a significant proportion of the watch batteries in use, and they have their own numbering system for Silver Oxide batteries which they use alongside the Universal naming syntax. Because of the high volume of batteries they supply, this numbering system is sometimes referred to as the “Swiss” battery number.

The numbering system itself has no logic, and does not provide any information about the size or composition of the battery. For example a 395 is a low drain battery of 9.5mm diameter x 2.7mm height, a 396 is a high drain battery of 7.9mm diameter x 2.6mm height.

The Universal naming syntax, although used internationally is sometimes referred to as the “Japanese” battery number. This is because Maxell, Panasonic, Sony and Toshiba all use the Universal system exclusively, and prominently print the code on their batteries.

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This is the 394 battery, which the packaging confirms is the SR936SW. However the cell only has the code 394 printed onto it. This would mean that someone who opens a watch and sees this cell would possibly not be able to identify a suitable replacement other than another Renata branded cell numbered 394

battery-24

Renata is part of the Swatch Group. ETA which make the vast majority of watch movements in use by the Swiss watch industry is also part of the Swatch Group. This is an ETA F03.111 movement, which is in common use in ladies sized watches. Above the battery there is the wording; “Battery 364. 6.8 x 2.1. 1.55V”. This makes it easy to identify which Renata battery to use as a replacement, but not so easy to know that you require a Universally named SR621SW

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The F03 series movement (as shown above this image) from ETA have for the most part replaced the 956 series movements. The example shown here is an ETA 956.112 movement. You can see that the negative battery contact has the sign for diameter (it looks like a 0 with a line through it) and 6.8, indentifying only the diameter of the correct battery size

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To combat the efforts of the Swatch Group, other brands, such as Rayovac shown here, have copied the Renata coding system to allow their batteries to be used as easily identifiable replacements. Energiser, Eveready, Varta and Duracell all use the Renata battery number, or a derivitive of it, too.

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Disposing of Watch Batteries

Watch battery cells contain a lot of chemicals that are harmful to the environment. Most batteries, even ones that have leaked, can be recycled. Silver Oxide batteries in particular are valuable, and in sufficient quantities can be sold for scrap to an appropriate recycling company.

2 Responses

  1. Vito Ignarra says:

    hello,

    i have a plant for the treatment of old watch batteries. Silver battery.

    I have a lot of lithium batteries (like 2032) that i want to sell. Can you give me a contact of company that involved in this business?

    best regards

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